<p>This book constitutes the refereed post-conference proceedings the 14th TPC Technology Conference&nbsp;on Performance Evaluation and Benchmarking, TPCTC 2022, which was held in Sydney, NSW, Australia, on September 5, 2022.</p><div>The 5 revised full papers presented were carefully selected from 12 submissions. The conference focuses on&nbsp;Pick and Mix Isolation&nbsp;Levels; Benchmarking&nbsp;considerations for Trustworthy and Responsible AI (Panel);&nbsp;Preliminary Scaling Characterization with TPCx-AI and&nbsp;New Initiatives.&nbsp;</div>